Hyperbranched polymers: growing richer in flavours with time.

Hyperbranched polymers (HBPs) have been studied for over three decades now; yet several interesting aspects continue to draw the attention of researchers worldwide. This is because of the simplicity of synthesis, their unique globular structure, and the numerous peripherally located functional groups that can be utilised to impart a variety of attributes, such as core-shell amphiphilicity, Janus amphiphilicity, clickable polymeric scaffolds, multifunctional crosslinkers, etc. Several reviews have been written on HBPs with a focus on synthetic strategies, structural diversity, and their potential applications; in this short feature article, we have taken an alternate approach to highlight some of the unique structural features of HBPs and their influence on the properties of HBPs. We also discuss their versatility and adaptability for the generation of several interesting functional polymeric systems. In the latter half, we focus on the utilisation of HBPs as multifunctional scaffolds, that rely on the numerous peripheral terminal groups. We conclude by drawing a structuro-functional analogy between the range of peripherally functionalised HBPs and other analogous, but more complex, polymeric systems. We believe that this review will serve as a visual sounding board that would encourage the development of several other applications for this class of unique polymers.

Amphiphilic Polymer Hydrogel-supported Catalysts: Tuning the Accessibility to the Catalytic Site by Molecular Jacketing.

Crosslinked amphiphilic hydrogels, prepared using a peripherally clickable hyperbranched polyester (HBP) and PEG-diazides of different molecular weights, were used to ligate Cu utilizing the triazole rings formed by the alkyne-azide click reaction. Since only a fraction of the peripheral propargyl groups in the HB polyester are needed to generate the crosslinked polymer, the remaining were clicked with different types of azides, such as MPEG azide, decyl azide or 4-methylbenzyl azide, to create a molecular jacket around the catalytic sites that can potentially influence the catalytic activity and reaction outcome. The crosslinked films ligated with Cu functioned very effectively to catalyse alkyne-azide click reactions, both in water and in organic solvents; the nature of the molecular jacket around the catalytic site had a clear influence the reaction rate, which depended upon the relative solubilities of the reactants. The gel-supported catalyst films were reused multiple times with little loss in catalytic activity.